Sunday, May 27, 2012

Alkanes, Alkenes, Alkynes & Halides, Nitro, Alcohol, Ketones, Aldehydes--By Nemo Jin

Alkane
--all carbon atoms bonded by single bond
--general form "CaH2a"
--alkyl groups: alkane lost one hydrogen



Alkene & Alkyne
--"ene" double bonded carbon atoms
--"yne" triple bonded carbon atoms
--same naming rules, give double/triple bond the lowest number
--larger groups are diagonal: trans
--larger groups are at either bottom or top: cis

Ex.
















 Ex.

















Functional Groups
--most reactive part of the molecule
--insoluble in water
--F is less reactive; Cl, Br are the most reactive ones
--NO2: tend to be explosive

           F = fluoro
            I = iodo
          Cl = chloro
          Br = bromo
      NO2 = nitro


Ex.





Alcohol
--using the largest chain containing the OH group
--replacing the "e" ending in parent hydrocarbon chain with "ol"
--give OH the lowest number

general form:


Ketone &Aldehyde
--Aldehyde:
   -double bonded oxygen at the end of main chain
   -change the ending to "al"
--Ketone:
   -double bonded oxygen that's not on either end
   -change the ending to "one"

for more info:
http://www.brooklyn.cuny.edu/bc/ahp/LAD/C4c/C4c_aldehydes.html








Thursday, May 24, 2012

Ester, Ether, Carboxylic Acids and Amines - By Sally Chen

Ester
- formed by 
- alcohol + carboxylic acid = ester
- fruity smell
- main chain:  drop "e" add "oate"
- counting starts on the double bonded oxygen end

Ether
- formed by 
- highly flammable
- insoluble in water
- good solvent for organic compounds
- side chain:  drop "e" add "oxy"
- counting starts on the oxygen end


Carboxylic acids
- formed by 
- can be neutralized by a base
- main chain:  drop "e" add "oic acid"
- counting starts on the double bonded oxygen end


Amines
- formed by 
- base
- primary amine = 1 carbon chain
  secondary amine = 2 carbon chain
  tertiary amine = 3 carbon chain
- closely related to NH3
- soluble
- fishy smell
- add "amino" between parent chain and side chain(s)
- counting:  whichever way makes the numbers smaller

I don't know how it just doesn't work out with the "Insert a Video" button, so here:
http://www.youtube.com/watch?v=mAjrnZ-znkY

Tuesday, May 15, 2012

Electronegativity, Polarity and VSEPR--By Tina Zhao

Electronegativity
- The attraction an atom has for the shared pair of electrons in a chemical bond
- It is the difference in electronegativity between two atoms that determines the degree of electron sharing which occurs between the two atoms
- Electonegativity refers to how much atoms want to gain electrons
- The top right corner of the periodic table has the highest electronegativity.Fluorine is the MOSTelectronegativity element, and the lowest electronegativity value is Francium with a value of 0.7
- If an atom has high Electronegativity value indicates that it readily pull on electrons in  a bond
-If an atom has low Electronegativity value indicates that it doesn't readily pull on electrons within a bond
- Electronectivity increase as you go across a row from left to right, and decrease as you go down a group
- The scale that is most commonly used to messure electronegativity is called the Pauling scalt , this scale range from 0.7 to 4.0
-High electronegativity values have high ionization energy because they strongly attract their valence electron and they are difficult to remove
- If the electronegativity difference < 0.5 it is a COVALENT bond
- If the electonegativity difference greater and equal the 0.5 or less and equal than 1.8 it is A POLAR COVALENT bond


Polarity
- Describes a molecule's electrical balance
- If there is an imbalance with electrical charge, then a molecule is polar
- If the electrical charge is the same strength on all sides of the molecule, then it is nonpolat


Polar Covalent Bonding
- electonegativity difference between 0.3 and 1.6 are considered to be covalent but with unequal sharing of elecreons , because the bond has slightly positive and slightly negative poles that form at each end
- Higher electronegativity will form a PARIAL NEGATIVE charge, and lower electronegativity will form a PARTIAL POSITIVE charge 
- An arrow sigh is usually used to indicate the migration of electons towards the more electronegativity

EX:
For CH3C1, C has a value of 2.5; H has a value of 2.1 and Cl has a value of 3.0.

...................H (2.1)
....................|
H(2.1) --------- C(2.5) ----------- Cl (3.0)
....................|
...................H (2.1)

Between the Hydrogen's and carbon there is a difference of 0.4, and between the carbon and chlorine there is a difference of 0.5.
VSEPR (The Valence Shell Electron Pair Repulsion

- For polyatomic molecules containing 3 or more atoms, one of the atoms is called the central atom to which other atoms are linked.
- The geometry of a molecule depends upon the total number of valence shell electron pairs (bonded or not bonded) present around the central atom and their repulsion due to relative sizes and shapes.
- If the central atom is surrounded by bond pairs only. It gives the symmetrical shape to the molecule.
- If the central atom is surrounded by lone pairs (lp) as well as bond pairs (bp) of then the molecule has a distorted geometry.
- The relative order of repulsion between electron pairs is as follows: lp – lp > lp – bp > bp – bp.
A lone pair is concentrated around the central atom while a bond pair is pulled out between two bonded atoms. As such repulsion becomes greater when a lone pair is involved.

  • linear molecule :with a 180o angle 
  • trigonal planar :with angle of 120



  • - If the electronegativity difference >1.8 it is an IONIC bond

    Sunday, May 13, 2012

    Chemical Bonding & Electronic Dot Structure -- by Ria Park

    Chemical Bonds

    Chemical Bonds 
    • are formed when the electrons of one atom are attracted by the nucleus if another atom.
    • are formed with various degrees of sharing of electrons between two atoms
    • COVALENT BOND is formed when the electrons are shared equally between two atoms
    • When the electrons of one atom are given away completely to another atom, both a positively charged ion and a negatively charged ion are formed
    • The force holding the two ions together is called an IONIC BONDS
    Covalent Bond
    Ionic Bond















    Lewis Structure
    • represents valance electrons.
    • uses dots to represent electrons, focuses on an atom's valence electrons only.
    • The electrons that are in pairs are Lone pairs or Nonbonding electrons.
    • These are not used to bond since the orbital they are in already has its full complement if electrons.
    • The unpaired electrons are Bonding electrons. They are capable of making one single covalent bond.
    • An atom needs to have 2 bonding electrons when we make a double covalent bond.
    • To make a triple covalent bond, an atom needs 3 bonding electrons.

    Now single covalent bond is forme
    Double Bond
    Triple Bond


    Example of Lewis Structure